By M W Roberts; J M Thomas; R I Bickley
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The molecules of block and graft copolymers are molecules of a better order; they include homopolymer subchains that are interconnected by means of chemical valence bonds. This structural com plexity is manifested within the strange habit of block and graft copolymers either in resolution and in bulk. many varieties of interac tions are attainable in block and graft copolymers within the strong kingdom.
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Additional info for Chemical physics of solids and their surfaces Volume 7; A review of the literature published up to mid-I 977
Delugeard, J. Desuche, and J. L. , 1976,B32,702. Charbonneau and Y . , 1976,B32,1420. J. L. Baudour and H. , 1977,B33, 1773. 44 Chemical Physics of Solids and their Surfaces in the liquid and gas phases allowing for internal rotation of the phenyl rings to avoid the energetically unfavourable intramolecular non-bonded contacts between orthohydrogens. 9 b, (depending on the lengths of the long molecular axis) and p between 91-95'. A'-Ray studies 45i 4 8 * 49 (which give only average conformations of the molecule) have shown that the molecules are planar in the crystalline phase, the strong intermolecular interactions forcing the molecules to remain in a sterically unfavourable conformation.
Mirskaya, I. E. Kozlova, and V. F. Bereznitskaya, Phys. Status Solidii, 1974,62b, 291. A. T. Hagler, E. Huler, and S. Lifson, J. Amer. Chem. ,1974,96, 531 9. A. T. Hagler and S. , 1974, EUO, 1336. F. A. Momany, L. M. Carruthers, R. F. McGuire, and H. A. Sheraga, J. Phys. , 1974,78, 23 K. , 1976, A32, 199. l3 l4 Is l6 l9 2o 21 1595. 26 Ref. a a a b b b C C C d* d d d e e e f f f f f g h i i i j D. E. Williams, J. Chem. , 1967, 47, 4680. * K. V. Mirskaya, I. E. Kozlova, and V. F. Bereznitskaya, Phys.
An area consisting of the two types of twinned domains is shown in Figure 18a. The ‘fourspot’ diffractionpattern was observed only when the selected area aperture includes domains of both types (Figure 18b). In Figure 18a it will be seen that in the pericline twinned domain, the twins form 24 Surface and Defect Properties of Solids Figure 17 (a) BF electron micrograph showing domains of albite-twin lamellae (running top lefi to bottom right) and domains of pericline-twin lamellae (running top right to bottom left) in microcline (Specimen 107).
Chemical physics of solids and their surfaces Volume 7; A review of the literature published up to mid-I 977 by M W Roberts; J M Thomas; R I Bickley