By R J Cremlyn
For the reason that its discovery in 1854, chlorosulfonic acid has confirmed that it's a actually flexible reagent. it's wide-spread as a sulfonating and chlorosulfonating agent, quite of natural compounds, and it presents beneficial artificial intermediates for plenty of branches of undefined. This ebook presents an in depth, modern account of the reactions of chlorosulfonic acid with aliphatic, fragrant and heterocyclic compounds; reactions with parts and inorganic compounds also are mentioned, besides using the reagent as a strong acid catalyst and dehydrating agent. ultimately, the economic makes use of and manufacture of chlorosulfonic acid are reviewed. The exact assurance during this e-book, coupled with the numerous references to fresh paintings, will make sure that it really is welcomed as a reference via artificial chemists in, for instance, the pharmaceutical, agrochemical, plastic and detergent industries. Researchers and their scholars in academia also will locate it a necessary addition to their bookshelves.
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Extra resources for Chlorosulfonic Acid
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32There is little precise mechanistic detail regarding these two reactions (Equations 30, 3 1). When the chlorosulfonation is performed under relatively mild conditions (low temperatures) using excess chlorosulfonic acid as solvent, it is possible that the initial On the other hand, at electrophilic species may be intact chlorosulfonic higher temperatures, (> 100 "C) chlorosulfonic acid slowly decomposes as indicated2' (Equation 32). CIS03H - HCI + SO3 (32) At higher temperatures, therefore, appreciable amounts of hydrogen chloride and sulfur trioxide may be present in the reagent.
Chlorosulfonic Acid by R J Cremlyn